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Influence of cashew nut shell liquid on corrosion and tribocorrosion behavior of metallic alloys

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Authors

Pino Hernández, Carlos Andrés
Amigó, Vicente
Klyatskina, Elizaveta
Ayala Garcia, Camilo
Álvarez, Oscar
Maranon, Alejandro
PORRAS HOLGUIN, ALICIA
Bermudez-Castañeda, Angela
Hernandez, Camilo
Esguerra Arce, Johanna
Abstract (Spanish)
El líquido de cáscara de anacardo (CNSL) se ha explorado en varias aplicaciones dentro de los principios de sostenibilidad y la economía circular de los residuos de productos agroindustriales. Para comprender las propiedades anticorrosivas y lubricantes de las soluciones CNSL, se llevó a cabo un enfoque multifacético que incorpora análisis electroquímicos, pruebas de inmersión, mediciones tribológicas y caracterización triboquímica para acero dulce AISI 1012, acero inoxidable AISI 420 y aleación de aluminio 6061. Análisis electroquímicos revelan un impacto positivo de CNSL, induciendo un cambio en el potencial de corrosión a valores más positivos y una disminución en la corriente de corrosión, lo que indica una inhibición efectiva de la corrosión para el acero inoxidable y la aleación de aluminio. En acero dulce, CNSL exhibe una inhibición de tipo mixto con una eficiencia que aumenta en correlación con la concentración de aceite. Las propiedades lubricantes del CNSL son evidentes según los coeficientes de fricción (COF) obtenidos y el régimen de lubricación elastohidrodinámico observado durante las pruebas tribológicas. Las pruebas triboquímicas demuestran una reducción del desgaste y una mejora del comportamiento de tribocorrosión en condiciones de deslizamiento. CNSL emerge como un mitigador de tribocorrosión prometedor, que demuestra beneficios multifacéticos. Los efectos dependientes de la concentración resaltan la necesidad de optimización en aplicaciones específicas, particularmente para materiales pasivos. CNSL no solo inhibe la corrosión mediante la formación de una película, sino que también proporciona una lubricación eficaz, reduciendo la fricción, el desgaste y la degradación químico-mecánica. Esta investigación aporta conocimientos valiosos a la ciencia de la corrosión. Propone aplicaciones prácticas para CNSL en diversos contextos industriales, mostrando su potencial como una solución sostenible y respetuosa con el medio ambiente para los desafíos de la tribocorrosión.
Abstract (English)
Cashew Nut Shell Liquid (CNSL) has been explored in several applications within the sustainability principles and circular economy of agro-industrial product waste. To understand the anticorrosive and lubricant properties of CNSL solutions, a multi-faceted approach, incorporating electrochemical analyses, immersion test, tribological measurements, and tribochemical characterization was carried out for mild steel AISI 1012, stainless steel AISI 420 and Aluminium Alloy 6061. Electrochemical analyses reveal a positive impact of CNSL, inducing a shift in corrosion potential to more positive values and a decrease in corrosion current, indicating effective corrosion inhibition for stainless steel and aluminium alloy. In mild steel, CNSL exhibits a mixed-type inhibition with efficiency increasing in correlation with oil concentration. The lubricating properties of CNSL are evident according to the coefficients of friction (COF) obtained and the elastohydrodynamic lubrication regime observed during tribological tests. Tribochemical tests demonstrate a reduction in wear and an improvement in tribocorrosion behavior under sliding conditions. CNSL emerges as a promising tribocorrosion mitigator, demonstrating multifaceted benefits. The concentration-dependent effects highlight the need for optimization in specific applications, particularly for passive materials. CNSL not only inhibits corrosion through film formation but also provides effective lubrication, reducing friction, wear, and chemical-mechanical degradation. This research contributes valuable insights to corrosion science. It proposes practical applications for CNSL in diverse industrial contexts, showcasing its potential as an environmentally friendly and sustainable solution for tribocorrosion challenges.
Extent
17 páginas
URI: https://repositorio.escuelaing.edu.co/handle/001/3135
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AK - Diseño Sostenible en Ingeniería Mecánica – DSIM
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