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Evaluación del proceso Fenton para el tratamiento de un agua sintética coloreada empleando calamina

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Evaluación del proceso Fenton para el tratamiento de un agua sintética coloreada empleando calamina.pdf (622.32 KB)
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Bermudez-Castañeda, Angela
Avendaño, Amalia
Acero Caicedo, Evelein Julieth
Abstract (Spanish)
La eliminación de colorantes sintéticos del medio acuoso representa un gran desafío ambiental debido a su compleja estructura química y baja biodegradabilidad. En esta investigación, se evaluó el proceso Fenton para el tratamiento de un agua coloreada con azul de metileno. En primer lugar, la aplicación del método Fenton homogéneo permitió seleccionar una dosis óptima de peróxido de hidrógeno de 2.94 mM (100 mg/L) y una relación óptima de Fe(II):H2O2 de 1:10, a partir de las cuales se obtuvo una eliminación de 99.9% del colorante. Posteriormente, se desarrolló el proceso Fenton heterogéneo usando como catalizador tres tipos de calamina provenientes de procesos de transformación del acero. Con la aplicación del proceso de Fenton heterogéneo y empleando la calamina tipo 2 (alto carbono) se reportó una degradación del colorante de 99.8%, una eliminación de la DQO de 86.3% y de 54.8% de COT, con una concentración óptima de 15 g/L de calamina, 2.94 milimolar (100mg/L) de peróxido de hidrógeno, con pH 3 y con 6 horas de reacción. De acuerdo con los resultados obtenidos, la utilización de la calamina como catalizador del proceso Fenton es una alternativa al uso de desechos en la industria del acero. También se demostró que el modelo cinético de primer orden se ajusta apropiadamente a la degradación de azul de metileno mediante los procesos de Fenton homogéneo y Fenton heterogéneo.
Abstract (English)
The removal of synthetic dyes from the aqueous medium represents a great environmental challenge because of its complex chemical structure and low biodegradability. In this research, was evaluated the Fenton process for the treatment of a solution colored with methylene blue. Firstly, the application of the homogeneous Fenton method allowed to select an optimal hydrogen peroxide dose of 2.94 mM (100 mg/L) and an optimum ratio of 1:10 of Fe(II):H2O2, from which a 99.9% removal of the dye was obtained. Later, the heterogeneous Fenton process was developed using as catalysts three types of mill scale from steel transformation processes. From this process, where mill scale type 2 (high carbon was used), a dye degradation of 99.8% was obtained, as well as a COD elimination of 86.3% and 54.8% of TOC were reported. The latest was achieved using an optimum concentration of 15 g/L of mill scale, 2.94 millimolar (100 mg/L) of hydrogen peroxide, at pH 3 and with 6 hours of reaction. According to those results, it is concluded that the use of mill scale as a catalyst for the Fenton process is an alternative for wastes in the steel industry in the frame of sustainability and circular economy. It was also demonstrated that the first-order kinetic model fits appropriately to the degradation of methylene blue, by homogeneous Fenton and heterogeneous Fenton processes.
Extent
22 páginas
URI: https://repositorio.escuelaing.edu.co/handle/001/3088
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AF - Centro de Estudios Ambientales
AK - Diseño Sostenible en Ingeniería Mecánica – DSIM
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